Recent Developments in the Structural Characterisation of Disordered, Mesoporous Solids

The accurate and precise characterisation of disordered, mesoporous solids continues to be an ongoing challenge due to the high level of complexity of such materials. Common, indirect methods, such as gas sorption and mercury porosimetry, still offer relatively cheap, and, most importantly, statistically representative characterisations of macroscopic samples. This work reviews and expands upon recent developments aimed at increasing, and cross-validating, the information obtained from such methods. This involves developing a better understanding of the pore-pore co-operative effects that emerge only in extensive, disordered pore networks to better interpret raw characterisation data, and to use these effects to deliver more information on the void space. This work also describes novel hybrid methods that also greatly increase the information that indirect methods can deliver on complex mesoporous solids.

The post Recent Developments in the Structural Characterisation of Disordered, Mesoporous Solids appeared first on Johnson Matthey Technology Review.

By |2018-06-18T14:15:02+00:00June 18th, 2018|Weld Engineering Services|Comments Off on Recent Developments in the Structural Characterisation of Disordered, Mesoporous Solids

Winning the battle against plastic pollution with International Standards on World Environment Day!

Plastic is an important material in our economy and daily lives. It has multiple functions that can help tackle a number of the challenges facing our society, be it packaging that ensures food safety and…

By |2018-06-04T07:27:40+00:00June 4th, 2018|Weld Engineering Services|Comments Off on Winning the battle against plastic pollution with International Standards on World Environment Day!

Accessibility and Location of Acid Sites in Zeolites as Probed by Fourier Transform Infrared Spectroscopy and Magic Angle Spinning Nuclear Magnetic Resonance

The understanding of location and accessibility of zeolite acid sites is a key issue in heterogeneous catalysis. This paper provides a brief overview of Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) characterisation of acidity in zeolites based on the application of test molecules with a diverse range of basicity and kinetic diameters….

The post Accessibility and Location of Acid Sites in Zeolites as Probed by Fourier Transform Infrared Spectroscopy and Magic Angle Spinning Nuclear Magnetic Resonance appeared first on Johnson Matthey Technology Review.

By |2018-06-01T08:50:19+00:00June 1st, 2018|Weld Engineering Services|Comments Off on Accessibility and Location of Acid Sites in Zeolites as Probed by Fourier Transform Infrared Spectroscopy and Magic Angle Spinning Nuclear Magnetic Resonance

Dynamic Nuclear Polarisation Enhanced Solid-State Nuclear Magnetic Resonance Studies of Surface Modification of γ-Alumina

Dynamic nuclear polarisation (DNP) gives large (>100-fold) signal enhancements in solid-state nuclear magnetic resonance (solid-state NMR) spectra via the transfer of spin polarisation from unpaired electrons from radicals implanted in the sample. This means that the detailed information about local molecular environment available for bulk samples from solid-state NMR spectroscopy can now be obtained for…

The post Dynamic Nuclear Polarisation Enhanced Solid-State Nuclear Magnetic Resonance Studies of Surface Modification of γ-Alumina appeared first on Johnson Matthey Technology Review.

By |2018-05-30T12:54:48+00:00May 30th, 2018|Weld Engineering Services|Comments Off on Dynamic Nuclear Polarisation Enhanced Solid-State Nuclear Magnetic Resonance Studies of Surface Modification of γ-Alumina
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