Toward Platinum Group Metal-Free Catalysts for Hydrogen/Air Proton-Exchange Membrane Fuel Cells

The status, concepts and challenges toward catalysts free of platinum group metal (pgm) elements for proton-exchange membrane fuel cells (PEMFC) are reviewed. Due to the limited reserves of noble metals in the Earth’s crust, a major challenge for the worldwide development of PEMFC technology is to replace Pt with pgm-free catalysts with sufficient activity and stability. The priority target is the substitution of cathode catalysts (oxygen reduction) that account for more than 80% of pgms in current PEMFCs. Regarding hydrogen oxidation at the anode, ultralow Pt content electrodes have demonstrated good performance, but alternative non-pgm anode catalysts are desirable to increase fuel cell robustness, decrease the H2 purity requirements and ease the transition from H2 derived from natural gas to H2 produced from water and renewable energy sources.

The post Toward Platinum Group Metal-Free Catalysts for Hydrogen/Air Proton-Exchange Membrane Fuel Cells appeared first on Johnson Matthey Technology Review.

By |2018-04-06T14:37:43+00:00April 6th, 2018|Weld Engineering Services|Comments Off on Toward Platinum Group Metal-Free Catalysts for Hydrogen/Air Proton-Exchange Membrane Fuel Cells

Guest Editorial

Historically, Johnson Matthey has had a long association with electrochemistry, and perhaps this was inevitable because of the importance of the platinum group metals (pgm) to Johnson Matthey’s early development. Platinum, in particular, has been incredibly useful in the field, because of its exceptional electrocatalytic activity and impressive inertness in most environments. Famously, Johnson Matthey…

The post Guest Editorial appeared first on Johnson Matthey Technology Review.

By |2018-04-05T14:01:00+00:00April 5th, 2018|Weld Engineering Services|Comments Off on Guest Editorial

Inter-Diffusion of Iridium, Platinum, Palladium and Rhodium with Germanium

The down-scaling of nanoelectronic devices to ever smaller dimensions and greater performance has pushed silicon-based devices to their physical limits. Much effort is currently being invested in research to examine the feasibility of replacing Si by a higher mobility semiconductor, such as germanium, in niche high-performance metal oxide semiconductor (MOS) devices. Before Ge can be adopted in industry, a suitable contact material for the active areas of a transistor must be identified. It is proposed that platinum group metal (pgm) germanides be used for this purpose, in a similar manner as metal silicides are used in Si technology. Implementation of Ge-based technology requires a thorough understanding of the solid-state interactions in metal/Ge systems in order to foresee and avoid problems that may be encountered during integration. We present a systematic study of the solid-state interactions in germanide systems of four of the pgms: iridium, platinum, palladium and rhodium. Our approach was essentially twofold. Firstly, conventional thin film couples were used to study the sequence of phase formation in the germanide systems. Conventional thin film couples were also used to identify and monitor the dominant diffusing species during the formation of some of the germanides as these can influence the thermal stability of a device. Secondly, we observed and analysed several aspects of the lateral diffusion reactions in these four systems, including activation energies and diffusion mechanisms. Lateral diffusion couples were prepared by the deposition of thick rectangular islands of one material on to thin films of another material. Rutherford backscattering spectrometry (RBS) and microprobe-Rutherford backscattering spectrometry (μRBS) were used to analyse several aspects of the thin film and lateral diffusion interactions respectively. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were also employed.

The post Inter-Diffusion of Iridium, Platinum, Palladium and Rhodium with Germanium appeared first on Johnson Matthey Technology Review.

By |2018-04-04T07:09:53+00:00April 4th, 2018|Weld Engineering Services|Comments Off on Inter-Diffusion of Iridium, Platinum, Palladium and Rhodium with Germanium

Spoiled for choice: an international guide to effective product labelling has just been updated

In the digital age, consumers have never been more informed about the products they buy, nor more hungry for information. Getting product information right is a key business strategy. A newly revised international…

By |2018-04-03T11:18:24+00:00April 3rd, 2018|Weld Engineering Services|Comments Off on Spoiled for choice: an international guide to effective product labelling has just been updated
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